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Chemistry

No. 2 (2025): FarDU ilmiy xabarlari jurnali (Tabiiy fanlar)

PREPARATION AND PROPERTIES OF POLYCOMPLEXONS CONTAINING AMINO AND CARBOXYL GROUPS(REVIEW)

Submitted
March 3, 2025
Published
2025-04-25

Abstract

This study focuses on some scientific works such as treatment of various wastewaters and effluents, ion exchange, gas separation, metal separation, etc., and provides a general overview of the latest scientific developments in the field of application and modification of membranes made of ion exchange sorbents and granular sorbents. Also, the production of anion exchangers based on polyethylenepolyamine and their alternative conditions were considered. Methods for modifying polyethylenepolyamine under heterogeneous conditions using modifiers containing amino and carboxyl groups were also described. Various ion exchange sorbents and membranes based on polyethylenepolyamine, methods for modifying polyethylenepolyamine, and the use of the obtained ion exchange sorbents and membranes are considered. Comparison of the sorption properties of ion exchange sorbents and sorbents based on polyethylenepolyamine used in industry was carried out.

References

  1. Ciesińska.W. et al. Preparation of sorbents from selected polymers //Polish Journal of Chemical Technology. – 2011. – Т. 13. – №. 1. – С. 51-54.
  2. Камбарова.Э.А, Бектенов.Н.А, Гавриленко.М.А,//Mодифицирование шунгитов полиэтиленполиамином и эпоксидной смолой для извлечения ионов свинца из сточных вод.Химический журнал казахстана, 2020. 170-179.
  3. Fontanals N, Borrull F., Marce RM Mixed-mode ion-exchange polymer sorbents in environmental analysis // Journal of Chromatography.A. – 2020. – T. 1609. – S. 460531.
  4. Wu.Q, Chen.S, Liu.H.//Effect of Activated Carbonide chemistry of polyethyleneimine-grafted polypropylene fiber on its CO 2 adsorption.RSC Advances. – 2014. – Т. 4. – №. 52. – С. 27176-27183.
  5. Dai.K et al. //Tunable synthesis of polyethylene polyamine modified lignin and application for efficient adsorption of Fe2+ in super Faollashtirilgan uglerodid system //Separation and Purification Technology. – 2021. – Т. 272. – С. 118950
  6. Dabrowski.A et al.//Selective removal of the heavy metal ions from waters and industrial wastewaters by ion-exchange method //Chemosphere. – 2004. – Т. 56. – №. 2. – С. 91-106.
  7. Sgreccia.E. et al. Stimuli-responsive amphoteric ion exchange polymers bearing carboxylic and amine groups grafted to a cross-linkable silica network //European Polymer Journal. – 2019. – Т. 112. – С. 255-262.
  8. Asadov.Z.H. et al. Synthesis and study of ionic-liquid type stutants based on diethylene triamine, polyethylene poliamine and alkyl halides (с7-с9, с14) //processes of petrochemistry and oil refining. – 2015. – Т. 16. – №. 3. – С. 199-207.
  9. Khoma.R.E. et al. Faollashtirilgan uglerodid-base and electrochemical behavior of monoethanolamine (polyethylenepolyamine)–citric Faollashtirilgan uglerodid–water solutions //J. Chem. Technol. – 2024. – Т. 32. – №. 1. – С. 30-42.
  10. Bekchanov.D. et al. Polyvinylсhloride‐based anion exchanger for efficient removal of chromium (VI) from aqueous solutions //Polymers for Advanced Technologies. – 2021. – Т. 32. – №. 10. – С. 3995-4004.
  11. Chen Y. W. et al. Preventing oxidation of iron sulfide minerals by polyethylene polyamines //Minerals Engineering. – 2006. – Т. 19. – №. 1. – С. 19-27.
  12. Dabrowski A. et al. Selective removal of the heavy metal ions from waters and industrial wastewaters by ion-exchange method //Chemosphere. – 2004. – Т. 56. – №. 2. – С. 91-106.
  13. Huang Q. et al. Preparation of polyethylene polyamine@ tannic activated carbonide
  14. encapsulated MgAl-layered double hydroxide for the efficient removal of copper (II) ions from aqueous solution //Journal of the Taiwan Institute of Chemical Engineers. – 2018. – Т. 82. – С. 92-101.
  15. Levashova V. I., Yangirova I. V. Synthesis and inhibitory properties of compositions based on boric Faollashtirilgan uglerodid, mixture of individual polyethylene polyamines and hexamethylenetetramine //Petroleum Chemistry. – 2016. – Т. 56. – С. 73-76.
  16. Li J., Bai T. The addition of Polyethylene-Polyamine surfFaollashtirilgan uglerode treated Carbon nanotube on the interfFaollashtirilgan uglerodial adhesion of Carbon fiber-reinforced Polyimide composite //Polymer-Plastics Technology and Engineering. – 2011. – Т. 50. – №. 13. – С. 1393-1397.
  17. Xie W., Wang R. Novel amino polymers-modified bamboo charcoal as solid adsorbents for co 2 capture //Petroleum & Coal. – 2014. – Т. 56. – №. 4.
  18. Al-Anber M., Al-Anber Z. A. Utilization of natural zeolite as ion-exchange and sorbent material in the removal of iron //Desalination. – 2008. – Т. 225. – №. 1-3. – С. 70-81.
  19. Yu.R et al. Polyoxyethylene Diamine Modification of Poly (amide-imide)-polyethylene Glycol Exhibits Excellent Hydrophilicity, Degradability, and Biocompatibility //Polymers. – 2022. – Т. 14. – №. 21. – С. 4694.
  20. Hubicki.Z, Kołodyńska.D Selective removal of heavy metal ions from waters and waste waters using ion exchange methods //Ion exchange technologies. – 2012. – Т. 7. – С. 193-240.
  21. Chen.D et al. Hyperbranched anion exchangers prepared from polyethylene polyamine modified polymeric substrates for ion chromatography //Journal of Chromatography A. – 2021. – Т. 1655. – С. 462508.
  22. Samy.T. S. A. Neocarzinostatin: effect of modification of side chain amino and carboxyl groups on chemical and biological properties //Biochemistry. – 1977. – Т. 16. – №. 25. – С. 5573-5578.
  23. Wang.B et al. Adsorption of cadmium ions from simulated battery wastewater by polyethylene polyamine-modified activated carbon //Water Science and Technology. – 2021. – Т. 84. – №. 12. – С. 3916-3927.
  24. Semenova.A.M et al. Carbalkoxilation of polyethylene polyamines with dialkyl carbonates //Russian Chemical Bulletin. – 2022. – Т. 71. – №. 1. – С. 146-151.
  25. Wang.Y.C. et al. Application of the flexible polyethylene polyamine-based covalent organic frameworks for fluorescence sensing nitrophenols and iodide ions //Journal of Molecular Structure. – 2025. – Т. 1323. – С. 140695.
  26. Chen.D et al. Preparation of compatibilizer PDABA-g-PEPA-O and its application in NR/MCC composites and analysis of compatibilization mechanism //Journal of Polymer Research. – 2023. – Т. 30. – №. 3. – С. 123.
  27. Dong.Q and others. Removal of hydrogen sulfide at room temperature by metal-free amine-functionalized mesoporous carbon: Effect of amines // Separation and purification technology – 2024. – T. 330. – S. 125152.
  28. Hubicki.Z, Kołodynska.D//Selective removal of heavy metal ions from waters and waste waters using ion exchange methods //Ion exchange technologies. – 2012. – Т. 7. – С. 193-240.
  29. Zhao.Z et al. Multiple functionalization of multi-walled carbon nanotubes with carboxyl and amino groups //Applied surface science. – 2013. – Т. 276. – С. 476-481.
  30. Xu.J. et al. Construction of a new continuous proton transport channel through a covalent crosslinking reaction between carboxyl and amino groups //International journal of hydrogen energy. – 2013. – Т. 38. – №. 24. – С. 10092-10103.
  31. Peng.C, Zhang.X.//Chemical functionalization of graphene nanoplatelets with hydroxyl, amino, and carboxylic terminal groups //Chemistry. – 2021. – Т. 3. – №. 3. – С. 873-888.
  32. Wright.W.W, Vanderkooi.J.M//Use of IR absorption of the carboxyl group of amino acids and their metabolites to determine pKs, to study proteins, and to monitor enzymatic activity //Biospectroscopy. – 1997. – Т. 3. – №. 6. – С. 457-467