TEMIR ASOSIDA METALL−ORGANIK ADSORBENTLAR OLISHNING SAMARALI USULLARI  (ADABIYOTLAR TAXLILI)

Muslima Karabayeva; Dilnoza Salixanova; Saodat Mirsalimova

Chemistry

No. 1 (2025): FarDU ilmiy xabarlari jurnali (TABIIY FANLAR)

EFFECTIVE METHODS FOR PRODUCING ORGANOMETALLIC ADSORBENTS BASED ON IRON

Muslima Karabayeva^▸^▾
Dilnoza Salixanova^▸^▾
Saodat Mirsalimova^▸^▾

PDF (Uzbek)

Submitted: January 27, 2025
Published: 2025-02-25

Abstract

Today, the environmental problem is one of the main issues facing humanity. The rapid development of various industries leads to the constant generation of significant volumes of toxic wastewater containing organic and inorganic pollutants, which seriously harm both people and the environment. Therefore, researching effective methods for wastewater treatment has become one of the urgent tasks for scientists worldwide. It is no coincidence that the President of the Republic of Uzbekistan, Shavkat Mirziyoyev, declared 2025 as the "Year of Environmental Protection and Green Economy."

This article, based on the above facts, highlights an analysis of the resources of recent years for the synthesis of metal-organic frameworks and processes for the synthesis of 3 types of adsorbents based on iron and organic substances (Fe-BTC- iron- 1,3,5-benzenetricarboxylate- framework, MOP-235- Iron terephthalate metal-organic framework, CHCFe -coconut husk-clay-ferrate composite). Information about raw materials, parameters and stages of the adsorbent production process is provided.

References

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L. Zeng, L. Xiao, Y. Long, and X. Shi, J Colloid Interface Sci, 2018, 516, 274-283.
J. Xu, W. Xing, H. Wang, W. Xu, Q. Ding, and L. Zhao, Analyst, 2016, 141, 2307-2319.
W. Li, X. Wu, S Li, W. Tang, and Y Chen, Appl. Surf. Sci, 2018, 436, 252-262.
S. Xiong, Y. Gong, S. Hu, S. Wu, W. Li, and Y. He, J. Mater. Chem. A, 2018, 6, 4752-4758
I. Lazaro, S. Haddad, J. Rodrigo-Munoz, R. Marshall, B. Sastre, and V. Del Pozo, ACS Appl. Mater. Interfaces, 2018, 10, 31146-31157
W. Ren, J. Gao, C. Lei, Y. Cai, Q. Ni, and J. Yao, Chem. Eng. J, 2018, 349, 766-774
Han, Qian & Wang, Zumin & Chen, Xiaoyu & Jiao, Chuangwei & Li, Haiyan & Yu, Ranbo. (2019). Facile Synthesis of Fe-based MOFs(Fe-BTC) as Efficient Adsorbent for Water Purifications. Chemical Research in Chinese Universities. 35. 10.1007/s40242-019-8415-z.
Lv Y., Zhan W., He Y., Wang Y., Kong X., Kuang Q., Xie Z., Zheng L., ACS Applied Materials &Interfaces, 2014, 6(6), 4186
E. Haque, J. Lee, I. Jang, Y. Hwang, J. Chang, R. and J. Jegal, J. Hazard. Mater, 2010, 181, 535-542
C. Cabello, M. Pico, F. Maya, M. del Rio, and G. Palomino, Chem. Eng. J, 2018, 346, 85-93.
J. Qiu, Y. Feng, X. Zhang, M. Jia, and J. Yao, J Colloid Interface Sci, 2017, 499, 151-158.
A. Mohammadi, A. Alinejad, B. Kamarehie, S. Javan, A. Ghaderpoury, and M. Ahmadpour, A, Int. J. Environ. Sci. Technol, 2017, 14(9), 1959-1968.
M. Aghajanzadeh, M. Zamani, H. Molavi, H. Manjili, H. Danafar and A. Shojaei,J. Inorg. Organomet. Polym. Mater, 2017 28, 177-186
18 S. Luo, and J. Wang, Environ Sci Pollut Res Int, 2018, 25(6), 5521-5528.
19 X. Li, W. Guo, Z. Liu, R. Wang, and H. Liu, Appl. Surf. Sci. 2016, 369, 130-136
T. Shen, J. Luo, S. Zhang, and X. Luo, Journal of Environmental Chemical Engineering, 2015, 3, 1372-1383.
Y. Lv, X. Zeng, and D. Cao, Chem. Eng. J, 2017, 323, 502- 511
L. Jin, X. Zhao, X. Qian, and M. Dong, J Colloid Interface Sci, 2018, 509, 245-253.
23 H. Abd El Salam, and T. Zaki, Inorg. Chim. Acta, 2018, 471, 203-210.
24 S. Zhao, D. Chen, F. Wei, N. Chen, Z. Liang, and Y. Luo, Ultrason. Sonochem, 2017, 39, 845-852.
25 X. Luo, X. Fu, Y. Du, J. Guo, and B. Li, Microporous Mesoporous Mat, 2017, 237, 268-274.,
26 T. Wang, P. Zhao, N. Lu, H. Chen, C. Zhang, and X. Hou, Chem. Eng. J, 2016, 295, 403-413
R. Rajak, M. Saraf, A. Mohammad, and S. Mobin, Journal of Materials Chemistry A,2017, 5, 17998-18011.
28 M. Azhar, H. Abid, H. Sun, V. Periasamy, M. Tade, and S. Wang, J Colloid Interface Sci, 2017, 490, 685-694.
29 X. Zhao, S. Liu, Z. Tang, H. Niu, Y. Gai, and W. Meng, Sci Rep, 2015, 5, 11849
DOI: 10.1039/C9NJ03370J
Adebayo, M.A., Jabar, J.M., Amoko, J.S. et al. Coconut husk-raw clay-Fe composite: preparation, characteristics and mechanisms of Congo red adsorption. Sci Rep 12, 14370 (2022). https://doi.org/10.1038/s41598-022-18763-y
Wang, P. et al. Magnetic permanently confned micelle arrays for treating hydrophobic organic compound contamination. J. Am. Chem. Soc. 131, 182–188 (2008).
Adebayo, M. A. & Areo, F. I. Removal of phenol and 4-nitrophenol from wastewater using a composite prepared from clay and Cocos nucifera shell: Kinetic, equilibrium and thermodynamic studies. Resour. Environ. Sustain. 3, 100020 (2021).

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[1] Xoldarov, X. M. (2023). O‘ZBEKISTON HUDUDIDAGI EKOLOGIK MUAMMOLAR VA ULARNI BARTARAF ETISH MASALALARI. Oriental Renaissance: Innovative, Educational, Natural and Social Sciences, 2. Retrieved from https://cyberleninka.ru/article/n/o-zbekiston-hududidagi-ekologik-muammolar-va-ularni-bartaraf-etish-masalalari

[2] L. Zeng, L. Xiao, Y. Long, and X. Shi, J Colloid Interface Sci, 2018, 516, 274-283.

[3] J. Xu, W. Xing, H. Wang, W. Xu, Q. Ding, and L. Zhao, Analyst, 2016, 141, 2307-2319.

[4] W. Li, X. Wu, S Li, W. Tang, and Y Chen, Appl. Surf. Sci, 2018, 436, 252-262.

[5] S. Xiong, Y. Gong, S. Hu, S. Wu, W. Li, and Y. He, J. Mater. Chem. A, 2018, 6, 4752-4758

[6] I. Lazaro, S. Haddad, J. Rodrigo-Munoz, R. Marshall, B. Sastre, and V. Del Pozo, ACS Appl. Mater. Interfaces, 2018, 10, 31146-31157

[7] W. Ren, J. Gao, C. Lei, Y. Cai, Q. Ni, and J. Yao, Chem. Eng. J, 2018, 349, 766-774

[8] Han, Qian & Wang, Zumin & Chen, Xiaoyu & Jiao, Chuangwei & Li, Haiyan & Yu, Ranbo. (2019). Facile Synthesis of Fe-based MOFs(Fe-BTC) as Efficient Adsorbent for Water Purifications. Chemical Research in Chinese Universities. 35. 10.1007/s40242-019-8415-z.

[9] Lv Y., Zhan W., He Y., Wang Y., Kong X., Kuang Q., Xie Z., Zheng L., ACS Applied Materials &Interfaces, 2014, 6(6), 4186

[10] E. Haque, J. Lee, I. Jang, Y. Hwang, J. Chang, R. and J. Jegal, J. Hazard. Mater, 2010, 181, 535-542

[11] C. Cabello, M. Pico, F. Maya, M. del Rio, and G. Palomino, Chem. Eng. J, 2018, 346, 85-93.

[12] J. Qiu, Y. Feng, X. Zhang, M. Jia, and J. Yao, J Colloid Interface Sci, 2017, 499, 151-158.

[13] A. Mohammadi, A. Alinejad, B. Kamarehie, S. Javan, A. Ghaderpoury, and M. Ahmadpour, A, Int. J. Environ. Sci. Technol, 2017, 14(9), 1959-1968.

[14] M. Aghajanzadeh, M. Zamani, H. Molavi, H. Manjili, H. Danafar and A. Shojaei,J. Inorg. Organomet. Polym. Mater, 2017 28, 177-186

[15] 18 S. Luo, and J. Wang, Environ Sci Pollut Res Int, 2018, 25(6), 5521-5528.

[16] 19 X. Li, W. Guo, Z. Liu, R. Wang, and H. Liu, Appl. Surf. Sci. 2016, 369, 130-136

[17] T. Shen, J. Luo, S. Zhang, and X. Luo, Journal of Environmental Chemical Engineering, 2015, 3, 1372-1383.

[18] Y. Lv, X. Zeng, and D. Cao, Chem. Eng. J, 2017, 323, 502- 511

[19] L. Jin, X. Zhao, X. Qian, and M. Dong, J Colloid Interface Sci, 2018, 509, 245-253.

[20] 23 H. Abd El Salam, and T. Zaki, Inorg. Chim. Acta, 2018, 471, 203-210.

[21] 24 S. Zhao, D. Chen, F. Wei, N. Chen, Z. Liang, and Y. Luo, Ultrason. Sonochem, 2017, 39, 845-852.

[22] 25 X. Luo, X. Fu, Y. Du, J. Guo, and B. Li, Microporous Mesoporous Mat, 2017, 237, 268-274.,

[23] 26 T. Wang, P. Zhao, N. Lu, H. Chen, C. Zhang, and X. Hou, Chem. Eng. J, 2016, 295, 403-413

[24] R. Rajak, M. Saraf, A. Mohammad, and S. Mobin, Journal of Materials Chemistry A,2017, 5, 17998-18011.

[25] 28 M. Azhar, H. Abid, H. Sun, V. Periasamy, M. Tade, and S. Wang, J Colloid Interface Sci, 2017, 490, 685-694.

[26] 29 X. Zhao, S. Liu, Z. Tang, H. Niu, Y. Gai, and W. Meng, Sci Rep, 2015, 5, 11849

[27] DOI: 10.1039/C9NJ03370J

[28] Adebayo, M.A., Jabar, J.M., Amoko, J.S. et al. Coconut husk-raw clay-Fe composite: preparation, characteristics and mechanisms of Congo red adsorption. Sci Rep 12, 14370 (2022). https://doi.org/10.1038/s41598-022-18763-y

[29] Wang, P. et al. Magnetic permanently confned micelle arrays for treating hydrophobic organic compound contamination. J. Am. Chem. Soc. 131, 182–188 (2008).

[30] Adebayo, M. A. & Areo, F. I. Removal of phenol and 4-nitrophenol from wastewater using a composite prepared from clay and Cocos nucifera shell: Kinetic, equilibrium and thermodynamic studies. Resour. Environ. Sustain. 3, 100020 (2021).