EFFECTIVE METHODS FOR PRODUCING ORGANOMETALLIC ADSORBENTS BASED ON IRON
Keywords:
metal-organic framework, adsorption, phase, mixture, grinding, drying.Abstract
Today, the environmental problem is one of the main issues facing humanity. The rapid development of various industries leads to the constant generation of significant volumes of toxic wastewater containing organic and inorganic pollutants, which seriously harm both people and the environment. Therefore, researching effective methods for wastewater treatment has become one of the urgent tasks for scientists worldwide. It is no coincidence that the President of the Republic of Uzbekistan, Shavkat Mirziyoyev, declared 2025 as the "Year of Environmental Protection and Green Economy."
This article, based on the above facts, highlights an analysis of the resources of recent years for the synthesis of metal-organic frameworks and processes for the synthesis of 3 types of adsorbents based on iron and organic substances (Fe-BTC- iron- 1,3,5-benzenetricarboxylate- framework, MOP-235- Iron terephthalate metal-organic framework, CHCFe -coconut husk-clay-ferrate composite). Information about raw materials, parameters and stages of the adsorbent production process is provided.
References
Xoldarov, X. M. (2023). O‘ZBEKISTON HUDUDIDAGI EKOLOGIK MUAMMOLAR VA ULARNI BARTARAF ETISH MASALALARI. Oriental Renaissance: Innovative, Educational, Natural and Social Sciences, 2. Retrieved from https://cyberleninka.ru/article/n/o-zbekiston-hududidagi-ekologik-muammolar-va-ularni-bartaraf-etish-masalalari
L. Zeng, L. Xiao, Y. Long, and X. Shi, J Colloid Interface Sci, 2018, 516, 274-283.
J. Xu, W. Xing, H. Wang, W. Xu, Q. Ding, and L. Zhao, Analyst, 2016, 141, 2307-2319.
W. Li, X. Wu, S Li, W. Tang, and Y Chen, Appl. Surf. Sci, 2018, 436, 252-262.
S. Xiong, Y. Gong, S. Hu, S. Wu, W. Li, and Y. He, J. Mater. Chem. A, 2018, 6, 4752-4758
I. Lazaro, S. Haddad, J. Rodrigo-Munoz, R. Marshall, B. Sastre, and V. Del Pozo, ACS Appl. Mater. Interfaces, 2018, 10, 31146-31157
W. Ren, J. Gao, C. Lei, Y. Cai, Q. Ni, and J. Yao, Chem. Eng. J, 2018, 349, 766-774
Han, Qian & Wang, Zumin & Chen, Xiaoyu & Jiao, Chuangwei & Li, Haiyan & Yu, Ranbo. (2019). Facile Synthesis of Fe-based MOFs(Fe-BTC) as Efficient Adsorbent for Water Purifications. Chemical Research in Chinese Universities. 35. 10.1007/s40242-019-8415-z.
Lv Y., Zhan W., He Y., Wang Y., Kong X., Kuang Q., Xie Z., Zheng L., ACS Applied Materials &Interfaces, 2014, 6(6), 4186
E. Haque, J. Lee, I. Jang, Y. Hwang, J. Chang, R. and J. Jegal, J. Hazard. Mater, 2010, 181, 535-542
C. Cabello, M. Pico, F. Maya, M. del Rio, and G. Palomino, Chem. Eng. J, 2018, 346, 85-93.
J. Qiu, Y. Feng, X. Zhang, M. Jia, and J. Yao, J Colloid Interface Sci, 2017, 499, 151-158.
A. Mohammadi, A. Alinejad, B. Kamarehie, S. Javan, A. Ghaderpoury, and M. Ahmadpour, A, Int. J. Environ. Sci. Technol, 2017, 14(9), 1959-1968.
M. Aghajanzadeh, M. Zamani, H. Molavi, H. Manjili, H. Danafar and A. Shojaei,J. Inorg. Organomet. Polym. Mater, 2017 28, 177-186
18 S. Luo, and J. Wang, Environ Sci Pollut Res Int, 2018, 25(6), 5521-5528.
19 X. Li, W. Guo, Z. Liu, R. Wang, and H. Liu, Appl. Surf. Sci. 2016, 369, 130-136
T. Shen, J. Luo, S. Zhang, and X. Luo, Journal of Environmental Chemical Engineering, 2015, 3, 1372-1383.
Y. Lv, X. Zeng, and D. Cao, Chem. Eng. J, 2017, 323, 502- 511
L. Jin, X. Zhao, X. Qian, and M. Dong, J Colloid Interface Sci, 2018, 509, 245-253.
23 H. Abd El Salam, and T. Zaki, Inorg. Chim. Acta, 2018, 471, 203-210.
24 S. Zhao, D. Chen, F. Wei, N. Chen, Z. Liang, and Y. Luo, Ultrason. Sonochem, 2017, 39, 845-852.
25 X. Luo, X. Fu, Y. Du, J. Guo, and B. Li, Microporous Mesoporous Mat, 2017, 237, 268-274.,
26 T. Wang, P. Zhao, N. Lu, H. Chen, C. Zhang, and X. Hou, Chem. Eng. J, 2016, 295, 403-413
R. Rajak, M. Saraf, A. Mohammad, and S. Mobin, Journal of Materials Chemistry A,2017, 5, 17998-18011.
28 M. Azhar, H. Abid, H. Sun, V. Periasamy, M. Tade, and S. Wang, J Colloid Interface Sci, 2017, 490, 685-694.
29 X. Zhao, S. Liu, Z. Tang, H. Niu, Y. Gai, and W. Meng, Sci Rep, 2015, 5, 11849
DOI: 10.1039/C9NJ03370J
Adebayo, M.A., Jabar, J.M., Amoko, J.S. et al. Coconut husk-raw clay-Fe composite: preparation, characteristics and mechanisms of Congo red adsorption. Sci Rep 12, 14370 (2022). https://doi.org/10.1038/s41598-022-18763-y
Wang, P. et al. Magnetic permanently confned micelle arrays for treating hydrophobic organic compound contamination. J. Am. Chem. Soc. 131, 182–188 (2008).
Adebayo, M. A. & Areo, F. I. Removal of phenol and 4-nitrophenol from wastewater using a composite prepared from clay and Cocos nucifera shell: Kinetic, equilibrium and thermodynamic studies. Resour. Environ. Sustain. 3, 100020 (2021).
Downloads
Published
Issue
Section
License
Copyright (c) 2025 Scientific journal of the Fergana State University
This work is licensed under a Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International License.
Most read articles by the same author(s)
- , SIMILARITIES AND DIFFERENCES OF COMMUNICATIVE AND PRAGMATIC INTENTIONS IN COMMERCIAL CORRESPONDENCE , Scientific journal of the Fergana State University: No. 2 (2024): Scientific journal of the Fergana State University (Social humanities sciences)
- , PROBLEMS OF SPEECH ETIQUETTE FORMATION IN PRESCHOOL CHILDREN , Scientific journal of the Fergana State University: No. 3 (2023): Scientific journal of the Fergana State University (Social humanities sciences)
- , THE MORAL POTENTIAL OF SOCIETY IN UZBEKISTAN AND ITS ROLE IN ENSURING SOCIAL DEVELOPMENT , Scientific journal of the Fergana State University: No. 4 (2023): FarDU ilmiy habarlari jurnali (Ijtimoiy gumanitar)
- , COMPETENCIES OF COGNITIVE PERCEPTION OF PROFESSIONAL KNOWLEDGE OF FUTURE TEACHERS , Scientific journal of the Fergana State University: No. 6 (2023): FarDU ilmiy xabarlari jurnali (Ijtimoy gumanitar fanlar)
- , , , , ASSESSMENT OF CHANGES IN AIR TEMPERATURE AND ATMOSPHERIC PRECIPITATION IN CONDITION OF CLIMATE CHANGE (Andijan region) , Scientific journal of the Fergana State University: No. 1 (2024): FarDU ilmiy xabarlar jurnali ilova to‘plam (GEOGRAFIYA)
- , , , , ENRICHMENT OF LOGON BENTONITE AND ANALYSIS OF MODIFIED ORGANOBENTONITES USING SCANNING ELECTRON MICROSCOPY , Scientific journal of the Fergana State University: No. 2 (2025): FarDU ilmiy xabarlari jurnali (Tabiiy fanlar)
- , PROBLEMS OF SPEECH ETIQUETTE FORMATION IN PRESCHOOL CHILDREN , Scientific journal of the Fergana State University: No. 3 (2023): Scientific journal of the Fergana State University (Social humanities sciences)
- , THE IMAGE OF HAZRAT KHIZR ALAYH SALAAM IN THE FOLK STORIES , Scientific journal of the Fergana State University: No. 5 (2024): Scientific journal of the Fergana State University (Social humanities sciences)
- Rustam Anorov, Ortiq Rahmonov, Safar Usmonov, Dilnoza Salixanova, Bobirjon Adizov, STUDY OF THE THERMOSALETASTABILITY OF DRILLING FLUIDS BASED ON ADSORBENTS OF OIL REFINING WASTE AND LOCAL CLAY , Scientific journal of the Fergana State University: No. 1 (2023): Scientific journal of the Fergana State University (Exact and natural sciences)
- , ON THE MODELS OF FOREIGN LANGUAGE TEACHING , Scientific journal of the Fergana State University: No. 3 (2023): Scientific journal of the Fergana State University (Social humanities sciences)