3,3'-DISULFANIDILBIS (1H-1,2,4-TRIAZOL-5-AMIN) SINTEZI

G‘iyosiddin Xayrullayev; Shahnoza Kadirova; Batirbay Torambetov; Sadoqat Botirova; Shahnoza Mavlonova

Chemistry

No. 3 (2022): Scientific journal of the Fergana State University

SYNTHESIS 3,3'-DISULFANEDIYLBIS(1H-1,2,4-TRIAZOL-5-AMINE)

G‘iyosiddin Xayrullayev^▸^▾
Shahnoza Kadirova^▸^▾
Batirbay Torambetov^▸^▾
Sadoqat Botirova^▸^▾
Shahnoza Mavlonova^▸^▾

PDF (Uzbek)

Submitted: July 11, 2023
Published: 2023-07-11

Abstract

The aim of this work is the synthesis of a new organic compound 3,3'-disulfanidylbis(1Н-1,2,4-triazole-5-amine) from 3-amino-5-mercapto-1,2,4-triazole. The article presents the optimal method for the synthesis of 3,3'-disulfanidylbis(1Н-1,2,4-triazole-5-amine) from 3-amino-5-mercapto-1,2,4-triazole and its significance. The results of infrared and Raman spectroscopic analysis of 3-amino-5-mercapto-1,2,4-triazole and 3,3'-disulfanidylbis(1H-1,2,4-triazole-5-amine) are presented.

References

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Yanli Gai, Xitong Chen, Huajun Yang, Yanxiang Wang, Xianhui Bu A new strategy for constructing a disulfidefunctionalized ZIF-8 analogue using structuredirecting ligand–ligand covalent interaction.
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[1] A. Kamal, MA. Syed, & SM. Mohammed. “Theraputic Potential of Benzothaizole” A Patent Review (2010- 2104). Informa healthcare, 25 (3), 2015.

[2] AK. Singh, & KR. Kandel, “Synthesis of Triazole Derivative: [4-(Benzylideneamino)-5-phenyl-4H-1,2,4- triazole-3-thiol],” J. Nepal Chem. Soc., 30, 2012.

[3] Артемьев Г.А., Уломский Е.Н., Русинов В.Л. “Оптимизация промышленных методов получения 5-амино-3-меркапто-1,2,4-триазола и 5-амино-3-метилтио-1,2,4-триазола”

[4] Frank Hipler, Manuela Winter, Roland A. Fischer N–S–H hydrogen bonding in 2-mercapto-5-methyl-1,3,4-thiadiazole. Synthesis and crystal structures of mercapto functionalised 1,3,4-thiadiazoles.

[5] Potts K.T. The chemistry of 1,2,4-triazoles.

[6] Yanli Gai, Xitong Chen, Huajun Yang, Yanxiang Wang, Xianhui Bu A new strategy for constructing a disulfidefunctionalized ZIF-8 analogue using structuredirecting ligand–ligand covalent interaction.

[7] K. Bahgat, & S. Fraihat, “Normal Coordinate Analysis, Molecular Structure, Vibrational, Electronic Spectra and NMR Investigation of 4-Amino-3-phenyl-1H-1,2,4- triazole-5(4H)-thione by Ab initio HF and DFT Method,” Spectrochimica Acta Part A: Mol. Biomol. Spectro., 135, 2015.

[8] А. В. Васильев, Е. В. Гриненко, А. О. Щукин, Т. Г. Федулина Инфракрасная спектроскопия органических и природных соединений. САНКТ-ПЕТЕРБУРГ СПбГЛТА 2007. Ст-16.