Cu(II) IONINING, SALITSILAMID HAMDA TRIETANOLAMIN BILAN KOMPLEKS BIRIKMASI SINTEZI VA KRISTALL TUZILISHI
##plugins.themes.bootstrap3.article.main##
Annotatsiya
Ushbu maqolada [Cu(L1)2(TEA)]·2H2O (Sal-salitsilamid, TEA-trietanolamin) kompleks birikmasi sintezi va uning kristall tuzilishi muhokama qilingan. Shu bilan birga, reaksiya unumining vaqt, harorat va reagentlar konsentratsiyaga bog‘liqligi ham o‘rganilgan. Sintez qilingan kompleks birikma IQ-Furye-spektroskopiya, UF-spektroskopiya, element analiz va rentgen strukturaviy analiz usullari yordamida o‘rganildi. Dunyodagi yetakchi ilmiy jamoalardan salitsilamid ishtirokida olingan koordinatsion birikmalar, ularning tuzilishi, fizik-kimyoviy xossalarini oʻrganish boʻyicha ishlarni A.Rao., D.Sribalan., G.Sandhya., K.Nonoyama., H. Ojima., M.Nonayama va ularning jamoalari olib borishgan. Bu olimlarning ishlaridan farqli ravishda ilk bor (aralash ligandli) salitsilamid va trietanolaminlarning mis bilan eritma muhitida [Cu(L1)2(TEA)]·2H2O tarkibli kompleks birikmasi sintez qilinib, monokristallari o‘stirildi va O‘zbekiston Respublikasi Fanlar akademiyasi Bioorganik kimyo institutining jamoaviy foydalanish markaziga o‘rnatilgan XtaLAB Synergy(Rigaki, Yaponiya) difraktometrida rentgenstrukturaviy tahlili o‘tkazildi.
##plugins.themes.bootstrap3.article.details##
Tsya robota litsenzuetsya vydpovídno do Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 xalqaro litsenziyasi.
Foydalaniladigan adabiyotlar
H.M.Shohidoyatov., H.O‘. Xo‘janiyozov., H.S.Tojimuhamedov. Organik kimyo-T. “Fan va texnologiya” nashriyoti,2014-yil, 800 bet.
J.Weder, C.Dillon, T.Hambley. Copper complexes of non-steroidal anti-inflammatory drugs: an opportunity yet to be realized. Coordination Chemistry Reviews. 2002;232(1-2):95–126.
Ruzmetov A. Kh., Ibragimov A.B., Myachina O.V., Kim R.N., Ibragimov B.T. Synthesis, crystal structure, Hirshfeld surface analysis and bioactivity of the Cu mixed-ligand complex with 4-hydroxybenzoic acid and monoehtanolamine // Chemical Data Collections. – 2022. – V.38. – p.100845.
Savithri K., Kumar B.V., Vivek H.K., Revanasiddappa H.D. Synthesis and Characterization of Cobalt(III) and Copper(II) Complexes of 2-((E)-(6-Fluorobenzo[d]thiazol-2-ylimino) methyl)-4-chlorophenol: DNA Binding and Nuclease Studies—SOD and Antimicrobial Activities. Int. J. Spectrosc. – 2018. – Vol.18, R. 8759372.
Hamamci Alisir S., Dege N., Tapramaz R. Synthesis, crystal structures and characterizations of three new copper (II) complexes including anti-inflammatory diclofenac. Acta Crystallogr. Sect. C Struct. Chem. – 2019. – 75(4), R. 388–397.
Krasnovskaya O., Naumov A., Guk D., Gorelkin P., Erofeev A., Beloglazkina E., and A. Majouga. Copper Coordination Compounds as Biologically Active Agents. Int. J. Mol. Sci. – 2020. – Vol.21(11), R. 1–37.
I.M. Primuhamedov. Organik kimyo darsligi.Toshkent O‘zSSR
“ Meditsina” nashriyoti, 1990-yil, 600 bet.
Khudoyberganov O.I., Ruzmetov A.X., Ibragimov A.B., Ashurov J.M., Khasanov Sh.B., Ibragimov B.T. Synthesis, crystal structure and Hirshfeld surface analysis of the binuclear Cu(II) complex with 4-nitrobenzoic acid and triethanolamine. Chemical Data Collections.100802. doi: 10.1016/j.cdc.2021.100802
Savitskaya L.K. X-ray structural analysis: textbook // Tomsk: SKK-Press, 2006, p.274.
Macrae C.F, Bruno I.J, Chisholm J.A. et. al. Mercury CSD 2.0 – new features for the visualization and investigation of crystal structures // J. Appl. Cryst. -2008. – V.41. -P.466-470.
Webster, F.X.; Kiemle, D.J. Spectrometric identification of organic compounds: John Wiley and Sons: New York; 2005.