Skip to main navigation menu Skip to main content Skip to site footer

Chemistry

No. 5 (2024): FarDU.Ilmiy xabarlar jurnali (Aniq va tabiiy fanlar)

SYNTHESIS AND CRYSTAL STRUCTURE OF THE COMPLEX COMPOUND OF Ni(II) ION WITH SALICYLAMIDE

Submitted
August 2, 2024
Published
2024-10-25

Abstract

This article discusses the synthesis of a complex compound containing [Ni(Sal)2(H2O)4] (Sal-salicylamide) and its crystal structure. The synthesized complex compound was studied by IR-Fourier spectroscopy, elemental analysis and X-ray structural analysis method. It was shown by X-ray structural analysis (RTT) method that nickel is coordinated with the selected ligand salicylamide through the oxygen atom of the carbonyl group, and that the hydroxyl group does not participate in the coordination. The stimulatory properties of the complex obtained by the reaction of Ni(II) ion with salicylamide were investigated and it was determined as a result of experiments that it increased compared to the initial ligand. This stimulator was applied to rice plants growing in saline soil in Khorezm region, and positive results were obtained. The surface analysis of the complex compound was carried out using the Crystal Explorer 17.5 program, and it was proved that intermolecular hydrogen bonds make a significant contribution (23.3%) to the structure of the compound in the crystalline state.

References

  1. Mjos K.D., Orvig C. Metallodrugs in Medicinal Inorganic Chemistry. Chem. Rev. – 2014. – Vol.114(8). – Р. 4540-4563.
  2. Krstic N.S., Nikolic R.S., Stankovic M.N., Nikolic N.G., Dordevic D.M. Coordination compounds of M(II) biometal ions with acid-type anti-inflammatory drugs as ligands–a review. Tropical Journal of Pharmaceutical Research. – 2015. – Vol.14(2). – P. 337-349.
  3. Khudoyberganov O.I., Ruzmetov A.X., Ibragimov A.B., Ashurov J.M., Khasanov Sh.B., Ibragimov B.T. Synthesis, crystal structure and Hirshfeld surface analysis of the binuclear Cu(II) complex with 4-nitrobenzoic acid and triethanolamine. Chemical Data Collections.100802. doi: 10.1016/j.cdc.2021.100802
  4. Ruzmetov A.Kh., Ibragimov A.B., Toderich K.N. Synthesis, structure of the Ni (II) complex of 4-hydroxybenzoic acid // European International Journal of Multidisciplinary Research and Management Studies. – 2022. – №12(2). – p.1-5
  5. Ruzmetov A. Kh., Ibragimov A.B., Myachina O.V., Kim R.N., Ibragimov B.T. Synthesis, crystal structure, Hirshfeld surface analysis and bioactivity of the Cu mixed-ligand complex with 4-hydroxybenzoic acid and monoehtanolamine // Chemical Data Collections. – 2022. – V.38. – p.100845.
  6. CrysAlisPro. Ver. 1.171.33.40, UK: Oxford Diffraction, 2007.
  7. T.Go’kturk., C.G.Topkaya., T.Ho’kelek., and R.Gup. ISSN 0022-4766, Journal of Structural Chemistry, 2024, Vol. 65, No. 1, pp. 15-27
  8. Sheldrick, G. M. Crystal structure refinement with SHELXL// Acta Cryst. 2015.–V. C71, P 3–8. doi:10.1107/S2053229614024218
  9. Ruzmetov A., Ibragimov B., Ashurov J., Boltayeva Z., Ibragimov B., Usmanov S. Synthesis, crystal structure and Hirshfeld surface analysis of hexaaqua nickel (II) bis (4-hydroxybenzoate) dihydrate // Acta Crystallographica Section E: Crystallographic Communications. – 2022. – V.78. – №6. – p.660-664.
  10. Alimnazarov B.Kh., Ashurov J.M., Ibragimov A.B., Mengnorov I.J., Sabirov V.K., Khodjaniyazov K.U. Hirshfeld surface analysis of the tetra-(2,4-D)- Cadmium(II) Ethylenediamine monohydrate // Доклады Академии Наук РУз. №2. -2021.– С. 82-85