АYRIM GETEROATOMLI ALDEGIDLARNI InBr3/Et3N/Et2O KATALITIK SISTEMASIDA ALKINILLASH JARAYONI
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Annotatsiya
Molekulasida geteroatom o‘rinbosarlar saqlagan quyidagi aldegidlar‒ tiofen-2-karbaldegid, 3-metiltiofen-2-karbaldegid, furan-2-karbaldegid, piridin-3-karbaldegid, хinolin-2-karbaldegid va 3-brom-4-piridinkarbaldegidlarning atsetilen, fenilatsetilen, geksin-1 va oktin-1 bilan ilk bor InBr3/Et3N/Et2O katalitik sistemasida atsetilen spirtlari sintez qilingan. Mahsulot unumiga boshlang‘ich moddalar mol miqdori nisbatlari, reaksiya davomiyligi, harorat, katalizator va erituvchilar tabiati ta’siri tizimli ravishda o‘rganilgan. Sintez qilingan yangi avlod atsetilen spirtlarining tarkibi, tozaligi va tuzilishi zamonaviy fizik-kimyoviy usullarda isbotlangan.
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