AYRIM AROMATIK ALDEGIDLARNI GRINYAR REAKTIVI YORDAMIDA ENANTIOSELEKTIV ALKINILLASH

Ziyadullayev Mirjalol Egamberdi o‘g‘li; Nurmanov Suvonqul Erhanovich; Bo‘riyev Forxod Xabibullayevich; Otamuxamedova Go‘zal Qamariddinovna

doi:10.56292/SJFSU/vol31_iss5/a111

Авторы

Ziyadullayev Mirjalol Egamberdi o‘g‘li

Chirchiq davlat pedagogika universiteti

https://orcid.org/0000-0001-7476-7202
Nurmanov Suvonqul Erhanovich

Mirzo Ulug‘bek nomidagi O‘zbekiston Milliy Universiteti
Bo‘riyev Forxod Xabibullayevich

Chirchiq davlat pedagogika universiteti
Otamuxamedova Go‘zal Qamariddinovna

Chirchiq davlat pedagogika universiteti

https://orcid.org/0009-0006-8141-9437

DOI:

https://doi.org/10.56292/SJFSU/vol31_iss5/a111

Ключевые слова:

ароматические ацетиленовые спирты, бензальдегид и его гетероатомные производные, реакции алкинилирования, каталитическая система, реактив Гриньяра, механизм реакции, выход продуктов.

Аннотация

Изучен метод синтеза нового поколения ароматических ацетиленовых спиртов реакцией алкинилирования бензальдегида и его различных производных, содержащих в молекулах атомы фтора, хлора, брома, кислорода, серы и азота, циклопропилэтеном в каталитической системе, приготовленной на основе этилмагнийхлорида, 2-(дибутиламино)-1-фенилпропанола-1 и трифторэтанола. Систематически изучена природа гетероатомов в молекуле выбранных альдегидов, влияние катализатора и растворителей, продолжительности реакции и температуры на выход продуктов. Предложены направление, стадии и механизмы реакции процесса алкинилирования. Состав, чистота и строение синтезированных соединений доказаны современными физико-химическими методами исследования.

Биографии авторов

Ziyadullayev Mirjalol Egamberdi o‘g‘li, Chirchiq davlat pedagogika universiteti

Chirchiq davlat pedagogika universiteti, Fizika va kimyo fakulteti, kimyo kafedrasi dotsenti, kimyo fanlari bo‘yicha falsafa doktori
Nurmanov Suvonqul Erhanovich, Mirzo Ulug‘bek nomidagi O‘zbekiston Milliy Universiteti

Mirzo Ulug‘bek nomidagi O‘zbekiston Milliy Universiteti, Kimyo fakulteti, organik va neft-gaz kimyo kafedrasi professori, texnika fanlari doktori
Bo‘riyev Forxod Xabibullayevich, Chirchiq davlat pedagogika universiteti

Chirchiq davlat pedagogika universiteti, Fizika va kimyo fakulteti, kimyo kafedrasi katta o‘qituvchisi
Otamuxamedova Go‘zal Qamariddinovna, Chirchiq davlat pedagogika universiteti

Chirchiq davlat pedagogika universiteti, Ilmiy tadqiqot, innovatsiyalar va ilmiy pedagogik kadrlar tayyorlash bo‘limi boshlig‘i, kimyo fanlari doktori

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