SYNTHESIS, STRUCTURE, AND HIRSHFELD SURFACE ANALYSIS OF THE METAL COMPLEX FORMED BY 2-HYDROXY-1-NAPHTHALDEHYDE WITH Ni2+ ION

doi:10.56292/SJFSU/vol31_iss4/a%p

Authors

Termiz davlat muhandislik va agrotexnologiyalar universiteti

https://orcid.org/0000-0002-3182-9407
Nematullo Izatillayev

Termiz davlat muhandislik va agrotexnologiyalar universiteti

https://orcid.org/0009-0003-9189-2453
Abdusamat Rasulov

Temiz iqtisodiyot va servis universiteti

https://orcid.org/0009-0005-3905-5556
Jamshid Ashurov

O’zbekiston Respublikasi Fanlar Akademiyasi Bioorganik kimyo instituti

https://orcid.org/0000-0002-4441-2803
Asal Ashurova

Termiz davlat muhandislik va agrotexnologiyalar universiteti

https://orcid.org/0009-0001-6603-3556

DOI:

https://doi.org/10.56292/SJFSU/vol31_iss4/a%25p

Keywords:

2-hydroxy 1-naphthaldehyde, ethylenediamine, nickel (II) sulphate, alcohol, complex, ligand, Hirshfeld

Abstract

A new metal complex compound of the composition [NiC24H18O2N2] was synthesized by the interaction of 2-hydroxy-1-naphthaldehyde (2-hnaph), ethylenediamine (EDA), and NiSO4 with solutions in ethyl alcohol. The composition, molecular and crystalline structure of this metal complex compound were investigated using X-ray structural analysis (XRD). A reaction occurs between the oxygen of the carbonyl in the aldehyde form of 2-naph and the amino (NH2) groups of ethylenediamine, releasing one molecule of water (>C=O + -NH2 → >C=N- +H2O). The resulting new ligand is bound to the central atom by two oxygen atoms and two nitrogen atoms. The bond length of Ni1-O1 is 1.850 (3) Å, and the Ni1-N1 and Ni1-N2 bonds are bonded at a distance of 1.832 (4) and 1.838 (4) Å, respectively. The angles between the atoms O1 - Ni1-O1' and O1 - Ni1-N1 are respectively 86.60 (16)0, 93.12 (16)0 and the parameters of the hydrogen bond are also given.

Author Biographies

, Termiz davlat muhandislik va agrotexnologiyalar universiteti

Termiz davlat muhandislik va agrotexnologiyalar universiteti, kafedra professori, kimyo fanlari doktori, professor.
Nematullo Izatillayev, Termiz davlat muhandislik va agrotexnologiyalar universiteti

Termiz davlat muhandislik va agrotexnologiyalar universiteti, assistent
Abdusamat Rasulov , Temiz iqtisodiyot va servis universiteti

Temiz iqtisodiyot va servis universiteti, kimyo fanlari bo’yicha falsafa (PhD) doktori, dotsent v/b.
Jamshid Ashurov, O’zbekiston Respublikasi Fanlar Akademiyasi Bioorganik kimyo instituti

O’zbekiston Respublikasi Fanlar Akademiyasi Bioorganik kimyo instituti, laboratoriya mudiri, kimyo fanlari doktori, professor.
Asal Ashurova , Termiz davlat muhandislik va agrotexnologiyalar universiteti

Termiz davlat muhandislik va agrotexnologiyalar universiteti, talaba

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