Cd(II) TUZINI 2-AMINO 1,3,4-TIADIAZOL BILAN KOMPLEKS BIRIKMASINING TUZILISHINI FIZIK-KIMYOVIY USULLAR YORDAMIDA O‘RGANISH
##plugins.themes.bootstrap3.article.main##
Annotatsiya
2-amino-1,3,4-tiadiazol va Cd(II) tuzi bilan [Cd2(L)3(NO3)3∙(H2O)2](NO3)2 tarkibli kompleks birikma sintez qilindi va sintez usuli ishlab chiqildi. Sintez qilingan kompleks birikmaning tarkibi, tuzilishi va xossalari fizik-kimyoviy metodlar: element analiz, IQ-spektroskopiya, termik analiz, rentgen tuzilish tahlili yordamida tahlil qilindi. Kompleks birikmaning tuzilishi Xirshfeld sirtini tahlili yordamida o‘rganildi. Xirshfeld yuza [Cd2(L)3(NO3)3∙(H2O)2](NO3)2 molekulasi uchun standart yuqori sirt aniqligidan foydalangan holda dnorm hisoblab chiqilgan. Rentgen tuzilish tahlil yordamida kristall strukturaning parametrlari, C atomiga bog‘langan vodorod atomlari hisoblangan. Kompleks birikma molekulalarining tekislikdagi va kristall yacheykada joylashuvi tahlil qilingan hamda birikmaning tuzilishi o‘rganilgan.
##plugins.themes.bootstrap3.article.details##
Tsya robota litsenzuetsya vydpovídno do Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 xalqaro litsenziyasi.
Foydalaniladigan adabiyotlar
Yusif E., Majeed A., Al-Sammarrae K., Salimon J., Abdullah B. (2013). Schiff base metal complexes: preparation, characterization and antibacterial activity. // ArabChem. (doi: 10.1016/j.arabjc.2013.06.006).
Li Y., Geng J., Liu Y., Yu S., Zhao G.(2013). Thiadiazole is a promising structure in medicinal chemistry.// London.-2013 .
Sharma A.K. (2011). Spectroscopic andmycological studies os Co(II),Ni(II) and Cu(II) complexes with 4-aminoantipyrine derivative // Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy.. http://dx.doi.org/10.1016/j.saa.2011.06.032.
Raper E.S. (1984). Copper complexes of heterocyclic thioamides and related ligands //Coordination Chemistry Reviews .-1984.- № 129(1-2).-P.91-156. http://dx.doi.org /10.1016/0010-8545(94)85019-4.
Harrowfield J.M. (2005). Biological coordination chemistry, a confluence of chemistry and biochemistry //Comptes Rendus Chimie. http://dx.doi.org/10.1016/j.crci.2004.12001.
Maw-Cherng Suen Chun-Wei.(2011). 1-catena-Poly[(l-2-amino-1,3,4-thia-diazole-j2N3:N4)di-l-chlorido-cadmium] //Technology, Chung-Li 320, Taiwan, Department of Chemistry, Chung-Yuan Christian University, Chung-Li,
Dudka A. P. (2015). Calibration of X-Ray diffractometer by the experimental comparisonmethod//CrystallographyReports. https://doi.org/10.1134/S1063774515040100