sg

Chemistry

No. 1 (2024): FarDU.Ilmiy xabarlar jurnali (Aniq va tabiiy fanlar)

SYNTHESIS OF BENZENE-1,2,4-TRIYL TRIS(2-((DIETHYLCARBAMOTHIOYL)THIO) ACETATE)

Submitted
April 8, 2024
Published
2024-04-18

Abstract

This article examined the reaction product of the chloroacetylation of oxyhydroquinone (1,2,4-trioxybenzene) from triatomic phenols in dimethylformamide (DMFA). Benzene-1,2,4-triyl tris(2-((diethylcarbamothioyl)thio)acetate) was produced as a consequence of the reaction. The obtained compound`s structure was verified using contemporary physico-chemical research techniques.

References

  1. Lowe, Andrew B.; Hoyle, Charles E.; Bowman, Christopher N. (2010). Thiol-yne click chemistry: A powerful and versatile methodology for materials synthesis. , 20(23), 4745–0. doi:10.1039/b917102a
  2. Choudhuri, Khokan; PRAMANIK, Milan; Mal, Prasenjit (2020). Noncovalent Interactions in C-S Bond Formation Reactions. The Journal of Organic Chemistry, acs.joc.0c01534–. doi:10.1021/acs.joc.0c01534
  3. Ishitani, H.; Saito, Y.; Nakamura, Y.; Yoo, W.-J.; Kobayashi, S., Knoevenagel Condensation of Aldehydes and Ketones with Alkyl Nitriles Catalyzed by Strongly Basic Anion Exchange Resins under Continuous-Flow Conditions. Asian J. Org. Chem. 2018, 7, 2061-2064.
  4. Liu, G.; Link, J. T.; Pei, Z.; Reilly, E. B.; Leitza, S.; Nguyen, B.; Marsh, K. C.; Okasinski, G. F.; von Geldern, T. W.; Ormes, M.; Fowler, K.; Gallatin, M., Discovery of Novel p-Arylthio Cinnamides as Antagonists of Leukocyte Function-Associated Antigen-1/Intracellular Adhesion Molecule-1 Interaction. 1. Identification of an Additional Binding Pocket Based on an Anilino Diaryl Sulfide Lead. J. Med. Chem. 2000, 43, 4025-4040.
  5. Carreno, M. C., Applications of Sulfoxides to Asymmetric Synthesis of Biologically Active Compounds. Chem. Rev. 1995, 95, 1717-1760. 6. Hongchen Liu, Lei Guo, Yamin Dai, Mengya Li, Dongwei Wang, Yun Li, Haisong Q., Facile fabrication of cellulose-based hydrophobic paper via Michael addition reaction. International Journal of Biological Macromolecules 253 (2023) 127513. https://doi.org/10.1016/j.ijbiomac.2023.127513
  6. Alma Viso, Roberto Fernández de la Pradilla. Alkylation of α-Sulfur-Containing Carbanions. Tetrahedron Letters, Volume 57, Issue 10, 2016. https://doi.org/10.1016/B978-0-323-96025-0.00031-4
  7. N. Miyaura, A. Suzuki, Chem. Rev. 95 (1995) 2457–2483
  8. Choriev, A.U.; Jurayev, R.S.; Abdushukurov, A.K.; Abdullayev, M.G. Synthesis of 2-Izopropyl-5-methylphenylcarboxymethylen Tartrate. Eng. Proc. 2023, 37, 57. https://doi.org/10.3390/ECP2023-14659
  9. Jurayev, R.S.; Choriev, A.U.; Qaxxorov, N.T. The Photometric Determination of Iron(III) with 2-Napthylcarboxymethylene Citrate. Eng. Proc. 2023, 48, 49. https://doi.org/10.3390/CSAC2023-14878.
  10. Jurayev, R.S.; Choriev, A.U.; Qaxxorov, N.T. Effect and Spectroscopic Analysis of Solutions in Trychloratsetylpyrogallol Synthesis. Chem. Proc. 2023, 14, x. https://doi.org/10.3390/ecsoc-27-16180
  11. Introduction to Organic Spectroscopy by L. M. Harwood and T. D. W. Claridge, OUP, Oxford, -1996.
  12. R. M. Silverstein, F. X. Webster, and D. J. Kiemle, Spectrometric Identification of Organic Compounds, Wiley, -2005
  13. Q.N.Axmedov, H.Y.Yo‘ldoshev, U.Ch.Axmedov, Organik kimyo usullari. 1-qism. Tоshkеnt 2013.