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Scientific information

No. 6- TOM (2023): SPECIAL ISSUE

PREPARATION AND PROPERTIES OF PERFLUOROACRYLIC AND PERFLUOROMETHACRYLIC ACID DERIVATIVES

Submitted
February 26, 2024
Published
2024-02-26

Abstract

Dehydrofluorination of available HFIBA derivatives at first sight seems to be the most convenient way of preparing PFMA derivatives. Yet, the so far reported attempts to carry out this reaction failed to give good results. Thermal dehydrofluorination of methyl ester over NAF yielded a mixture of PFMA ester and the starting saturated ester, which is difficult to separate.

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