STUDYING THE STRUCTURE OF A COMPLEX COMPOUND OF Cd(II) SALT WITH 2-AMINO-1,3,4-THIADIAZOLE BY PHYSICAL-CHEMICAL METHODS
Keywords:
Coordination compound, ligand, metal, IR spectrum, X-ray diffraction analysis, thermal analysis, endothermic, exothermic effects, composition, properties and structure.Abstract
A complex compound consisting of [Cd2(L)3(NO3)3∙(H2O)2](NO3)2 with 2-amino-1,3,4-thiadiazole and a Cd(II) salt was synthesized and a synthesis method was developed. The composition, structure and properties of the synthesized complex were analyzed using physicochemical methods: elemental analysis, IR spectroscopy, thermal analysis, X-ray diffraction analysis. The structure of the complex compound was studied by Hirshfeld surface analysis. The crystal structure parameters, hydrogen atoms bonded to the C atom, were calculated by X-ray diffraction analysis. The arrangement of the molecules of the complex compound in the plane and in the crystal cell was analyzed, and the structure of the compound was studied.
References
Yusif E., Majeed A., Al-Sammarrae K., Salimon J., Abdullah B. (2013). Schiff base metal complexes: preparation, characterization and antibacterial activity. // ArabChem. (doi: 10.1016/j.arabjc.2013.06.006).
Li Y., Geng J., Liu Y., Yu S., Zhao G.(2013). Thiadiazole is a promising structure in medicinal chemistry.// London.-2013 .
Sharma A.K. (2011). Spectroscopic andmycological studies os Co(II),Ni(II) and Cu(II) complexes with 4-aminoantipyrine derivative // Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy.. http://dx.doi.org/10.1016/j.saa.2011.06.032.
Raper E.S. (1984). Copper complexes of heterocyclic thioamides and related ligands //Coordination Chemistry Reviews .-1984.- № 129(1-2).-P.91-156. http://dx.doi.org /10.1016/0010-8545(94)85019-4.
Harrowfield J.M. (2005). Biological coordination chemistry, a confluence of chemistry and biochemistry //Comptes Rendus Chimie. http://dx.doi.org/10.1016/j.crci.2004.12001.
Maw-Cherng Suen Chun-Wei.(2011). 1-catena-Poly[(l-2-amino-1,3,4-thia-diazole-j2N3:N4)di-l-chlorido-cadmium] //Technology, Chung-Li 320, Taiwan, Department of Chemistry, Chung-Yuan Christian University, Chung-Li,
Dudka A. P. (2015). Calibration of X-Ray diffractometer by the experimental comparisonmethod//CrystallographyReports. https://doi.org/10.1134/S1063774515040100
Downloads
Published
Issue
Section
License
Copyright (c) 2024 Scientific journal of the Fergana State University
This work is licensed under a Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International License.