SYNTHESIS AND CRYSTAL STRUCTURE OF THE COMPLEX COMPOUND OF Cu(II) ION, SALICILAMIDE AND TRIETHANOLAMINE
Main Article Content
Abstract
The article discusses the synthesis of the complex [Cu(L1)2(TEA)]·2H2O (Sal-salicylamide, TEA-triethanolamine) and its crystal structure. At the same time, the dependence of the reaction yield on time, temperature and concentration of reagents was also studied. The synthesized complex compound was studied by Fourier transform infrared spectroscopy, UV spectroscopy, elemental analysis and X-ray diffraction. A. Rao., D. Sribalan., G. Sandhya., K. Nonoyama., H. Ojima., M. Nonayama and their teams. In contrast to the work of these scientists, for the first time (with mixed ligands) a complex compound of salicylamide and triethanolamines of the composition [Cu(L1)2(TEA)]·2H2O was synthesized in a solution with copper; single crystals were grown and X-ray diffraction analysis was carried out at the Institute of Bioorganic Chemistry of the Academy of Sciences RUz on the XtaLAB Synergy diffractometer (Rigaki, Japan), installed in a public access center.
Article Details
This work is licensed under a Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International License.
References
H.M.Shohidoyatov., H.O‘. Xo‘janiyozov., H.S.Tojimuhamedov. Organik kimyo-T. “Fan va texnologiya” nashriyoti,2014-yil, 800 bet.
J.Weder, C.Dillon, T.Hambley. Copper complexes of non-steroidal anti-inflammatory drugs: an opportunity yet to be realized. Coordination Chemistry Reviews. 2002;232(1-2):95–126.
Ruzmetov A. Kh., Ibragimov A.B., Myachina O.V., Kim R.N., Ibragimov B.T. Synthesis, crystal structure, Hirshfeld surface analysis and bioactivity of the Cu mixed-ligand complex with 4-hydroxybenzoic acid and monoehtanolamine // Chemical Data Collections. – 2022. – V.38. – p.100845.
Savithri K., Kumar B.V., Vivek H.K., Revanasiddappa H.D. Synthesis and Characterization of Cobalt(III) and Copper(II) Complexes of 2-((E)-(6-Fluorobenzo[d]thiazol-2-ylimino) methyl)-4-chlorophenol: DNA Binding and Nuclease Studies—SOD and Antimicrobial Activities. Int. J. Spectrosc. – 2018. – Vol.18, R. 8759372.
Hamamci Alisir S., Dege N., Tapramaz R. Synthesis, crystal structures and characterizations of three new copper (II) complexes including anti-inflammatory diclofenac. Acta Crystallogr. Sect. C Struct. Chem. – 2019. – 75(4), R. 388–397.
Krasnovskaya O., Naumov A., Guk D., Gorelkin P., Erofeev A., Beloglazkina E., and A. Majouga. Copper Coordination Compounds as Biologically Active Agents. Int. J. Mol. Sci. – 2020. – Vol.21(11), R. 1–37.
I.M. Primuhamedov. Organik kimyo darsligi.Toshkent O‘zSSR
“ Meditsina” nashriyoti, 1990-yil, 600 bet.
Khudoyberganov O.I., Ruzmetov A.X., Ibragimov A.B., Ashurov J.M., Khasanov Sh.B., Ibragimov B.T. Synthesis, crystal structure and Hirshfeld surface analysis of the binuclear Cu(II) complex with 4-nitrobenzoic acid and triethanolamine. Chemical Data Collections.100802. doi: 10.1016/j.cdc.2021.100802
Savitskaya L.K. X-ray structural analysis: textbook // Tomsk: SKK-Press, 2006, p.274.
Macrae C.F, Bruno I.J, Chisholm J.A. et. al. Mercury CSD 2.0 – new features for the visualization and investigation of crystal structures // J. Appl. Cryst. -2008. – V.41. -P.466-470.
Webster, F.X.; Kiemle, D.J. Spectrometric identification of organic compounds: John Wiley and Sons: New York; 2005.