ТURLI XIL TABIATGA EGA KETONLARNI ENANTIOSELEKTIV ETINILLASH ASOSIDA ATSETILEN SPIRTLARI SINTEZI
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Annotatsiya
Ilk bor TBAF·3H2О/DMSO/H2О katalitik sistemasida ayrim ketonlarni kalsiy karbid yordamida enantioselektiv etinillash reaksiyasi bo‘yicha terminal atsetilen spirtlari sintez qilingan. Mahsulot unumiga erituvchilar, katalizator, reagent va substratlarning tabiati va miqdorlari ta’siri o‘rganilgan. Reaksiyalarni boshqarish va nazorat qilishning eng muqobil sharoitlari aniqlangan. Tanlangan ketonlarning mahsulot hosil bo‘lish samaradorlik qatori ishlab chiqilgan. Sintez qilingan terminal atsetilen spirtlari identifikatsiyalangan, tarkibi, tozaligi, tuzilishi va xususiy konstantalari zamonaviy fizik-kimyoviy usullarda isbotlangan.
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